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HIDROGENACIÓN SELECTIVA DE CITRAL EN FASE LÍQUIDA SOBRE CATALIZADORES Ir-Fe/TiO 2 REDUCIDOS A ALTA TEMPERATURA SELECTIVE HYDROGENATION OF CITRAL IN LIQUID PHASE OVER Ir-Fe/TiO2 REDUCED AT HIGH TEMPERATURE
The citral hydrogenation was studied over Ir-Fe/TiO2 catalysts reduced at 773 K (HTR: high temperature reduction). The catalysts synthesis was made using H2IrCl6 aqueous solution to get ca. 1% wt Ir load and by impregnating FeCl3 solution to obtain bimetallic catalysts. The results showed that all of the studied Ir/TiO2 and Fe–Ir/TiO2 catalysts display high selectivities (ca. 100%) towards the unsaturated alcohols (geraniol and nerol) during citral hydrogenation. Solids were charac127 REVISTA COLOMBIANA DE QUIMICA, VOLUMEN 34, No. 2 DE 2005 * Grupo de Catalisis (GC-UPTC), Escuela de Quimica, Facultad de Ciencias, Universidad Pedagogica y Tecnologica de Colombia, Tunja, Colombia. Correo electronico: hrojas@tunja.uptc.edu.co ** Departamento de Quimica, Facultad de Ciencias, Universidad Nacional de Colombia, Bogota D.C., Colombia. *** Laboratorio de Catalisis III, Departamento de Fisico-Quimica, Facultad de Ciencias Quimicas, Universidad de Concepcion, Concepcion, Chile.