In this paper we analyze the role of the Corporate Volunteer within the Corporate Social Responsibility strategies from a literature review on the topic. It begins with a conceptual and historical review of CSR. Then we review the VC conceptual analyzing the various changes that have occurred in the evolution of this. Then we review the main motivations behind the volunteers to perform such tasks. Although studies have been qualitative and quantitative, and research is necessary to delve into, why do some employees and not others?, And it becomes necessary to inquire whether acquired behaviors or are they driven organizations or have been acquired in previous stages to the workplace?.