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KINETICS OF THE ESTERIFICATION OF MALEIC ANHYDRIDE WITH CASTOR OIL.

Acceso Cerrado
ID Minciencias: ART-0000087807-5796
Ranking: ART-ART_C

Abstract:

Kinetics reaction between castor oil and maleic anhydride without condensation and cat- alyst was studied. On the other hand, the products concentration, kinetics and thermodynamics para- meters were determined using mathematical model- ing and were validated with experimental data. The reaction was carried out in a semi-batch reactor at constant temperature. The reaction was conducted through the determining of the acid number (ASTM D4662-03), and showed first order kinetics with re- spect to the anhydride. For the modified oil, the hy- droxyl value (OHv) was quantified through titration following (ASTM D4274-05). The distribution of mo- lecular weights was determined using gel permeation chromatography (GPC), and functional group analy- sis was determined using infrared spectroscopy (IR).

Tópico:

Petroleum Processing and Analysis

Citaciones:

Citations: 11
11

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FuenteNo disponible
Cuartil año de publicaciónNo disponible
Volumen41
Issue1
Páginas11 - 15
pISSNNo disponible
ISSNNo disponible
Perfil OpenAlexNo disponible

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