The following paper is a detailed study of the optical properties of HEMA-DRI3 from optical birefringence can be induced azopolymeric material. Based on the method of two-photon absorption, anisotropy is generated due to the reorientation of the chromophores in the sample of HEMA-DR13. Using allow-power laser He-Ne, and a laser Nd-YAG medium power, it was possible to implement an optical system which allows observing the subsequent quantification of photoinduced bireftingence in said material. Subsequently comparing the results obtained with different theoretical models, thereby determining the characteristic times (time of excitation and relaxation time) of HEMA-DR13. Additionally, a study of the response signal based on the excitation power and the temperature of the material being able to obtain the relationship between this variables and the intensity of bircfringence.