The low-lying level structure of $^{63}\mathrm{V}$ was studied for the first time by the inelastic proton scattering and the proton knock-out reaction in inverse kinematics. The comparison of the newly observed $\ensuremath{\gamma}$-ray transitions at 696(8) keV and 889(16) keV with our shell-model calculations using the Lenzi-Nowacki-Poves-Sieja interaction established two excited states proposed to be the first $11/{2}^{\ensuremath{-}}$ and $9/{2}^{\ensuremath{-}}$ levels. The $(p,{p}^{\ensuremath{'}})$ excitation cross sections were analyzed by the coupled channel formalism assuming pure quadrupole as well as quadrupole+hexadecapole deformations. This resulted in large deformation parameters placing $^{63}\mathrm{V}$ in the island of inversion located below $^{68}\mathrm{Ni}$.