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Preferred Growth Direction by PbS Nanoplatelets Preserves Perovskite Infrared Light Harvesting for Stable, Reproducible, and Efficient Solar Cells

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ID Minciencias: ART-0000281204-171
Ranking: ART-ART_A1

Abstract:

Abstract Formamidinium‐based perovskite solar cells (PSCs) present the maximum theoretical efficiency of the lead perovskite family. However, formamidinium perovskite exhibits significant degradation in air. The surface chemistry of PbS has been used to improve the formamidinium black phase stability. Here, the use of PbS nanoplatelets with (100) preferential crystal orientation is reported, to potentiate the repercussion on the crystal growth of perovskite grains and to improve the stability of the material and consequently of the solar cells. As a result, a vertical growth of perovskite grains, a stable current density of 23 mA cm −2 , and a stable incident photon to current efficiency in the infrared region of the spectrum for 4 months is obtained, one of the best stability achievements for planar PSCs. Moreover, a better reproducibility than the control device, by optimizing the PbS concentration in the perovskite matrix, is achieved. These outcomes validate the synergistic use of PbS nanoplatelets to improve formamidinium long‐term stability and performance reproducibility, and pave the way for using metastable perovskite active phases preserving their light harvesting capability.

Tópico:

Perovskite Materials and Applications

Citaciones:

Citations: 31
31

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Información de la Fuente:

SCImago Journal & Country Rank
FuenteAdvanced Energy Materials
Cuartil año de publicaciónNo disponible
Volumen10
Issue46
PáginasNo disponible
pISSNNo disponible
ISSN1614-6840

Enlaces e Identificadores:

Minciencias IDART-0000281204-171Scienti ID0001596075-8Scienti ID0000281204-171
Scienti URLhttps://onlinelibrary.wiley.com/doi/10.1002/aenm.202002422Openalex URLhttps://openalex.org/W3095540874Open_access URLhttps://biblio.ugent.be/publication/8699758/file/8699759
Doi URLhttps://doi.org/10.1002/aenm.202002422
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