Most electrical and electronic equipment contain a printed circuit board (PCB), which is the board on which microelectronic components are mounted. The PCBs of obsolete and discarded electrical and electronic equipment are a material of great value due to their high metal content that is of commercial importance (i.e., Au, Ag, Pd, Pt, Ir, Ti, Ge, Si, Al, Cu, Ni, Zn, Fe, Sn, As, and Pb). Hydrometallurgical and pyrometallurgical methods have been used to extract metals from PCBs; however, these methods have energy and environmental disadvantages, which is why in recent years sustainable alternatives have been sought. Among these alternatives are the biological methods that contemplate the use of microorganisms and plants to recover metals from PCBs. In this review, only studies specifying the use of bacteria, fungi, and plants in the recovery of metals from the PCBs of computers and cell phones were considered, since the metallic composition of these plates varies according to the electronic equipment. In addition, the challenges and recommendations for these biotechnological processes to be improved and implemented at the industrial level in the coming years are discussed.