In this chapter, different types of β-tricalcium phosphate (β-TCP)/Ch coatings were deposited via an electrodeposition method. The β-TCP/Ch coatings could be considered as promising materials for biomedical industry in temporal invasive prosthesis applications as they can effectively improve the bone/prosthesis interfaces. The β-TCP/Ch coatings were deposited via cathodic electrodeposition on AISI stainless steel (316L SS) substrates (12 mm of diameter and 5 mm of thickness). From the scanning electron microscope (SEM) micrographs, it was possible to observe the topography changes on the surface coatings in relation with different chitosan percentages. These changes were associated with the results of the morphological analysis of β-TCP/Ch coatings performed by using atomic force microscopy (AFM) analysis, which showed the decrease of grain size and roughness as a function of chitosan percentage. Different mechanical properties such as hardness were obtained for the β-TCP/Ch coatings.