Logotipo ImpactU
Autor

Conduction electrons mediating the evolution from antiferromagnetic to ferromagnetic ordering in Gd (Co 1−y Fe y )2Zn 20

Acceso Cerrado
ID Minciencias: ART-0000694886-91
Ranking: ART-ART_A2

Abstract:

${\mathrm{GdFe}}_{2}{\mathrm{Zn}}_{20}$ is a complex cagelike compound with an unusually high ferromagnetic ordering temperature (${T}_{C}=86$ K) for a very diluted ${\mathrm{Gd}}^{3+}$ magnetic sublattice, embedded in a matrix that features strong electron-electron correlations. Here, we report on a magnetic and electronic study of the substitutional intermetallic system $\mathrm{Gd}{({\mathrm{Co}}_{1\ensuremath{-}y}{\mathrm{Fe}}_{y})}_{2}{\mathrm{Zn}}_{20}$ combining magnetization measurements plus first-principles density functional theory (DFT) calculations with temperature-dependent electron spin resonance (ESR). After accounting for electron-electron correlations and itinerant molecular field effects, the ESR results indicate that the exchange interaction between the ${\mathrm{Gd}}^{3+}$ is processed via a single band of $d$-type electrons at the Fermi level and the exchange interaction is covalent in nature $[J{(0)}_{fd}<0]$ with a strong conduction electron ($ce$) momentum transfer dependence $[{J}_{fd}(q)]$. The DFT calculations support this scenario by indicating a major contribution of $d$-type $ce$ at the Fermi level and a spin polarization in $(\text{Y},\mathrm{Gd}){\mathrm{Fe}}_{2}{\mathrm{Zn}}_{20}$ wherein the most stable configuration is antiferromagnetic between ${\mathrm{Gd}}^{3+}$ and $ce$ spins. Our results demonstrate that the standard Ruderman-Kittel-Kasuya-Yosida mechanism cannot explain the ferromagnetic behavior of ${\mathrm{GdFe}}_{2}{\mathrm{Zn}}_{20}$ and a superexchangelike mechanism is proposed for this magnetic interaction. An ``extended phase diagram'' for the double substitution sequence ${\mathrm{YCo}}_{2}{\mathrm{Zn}}_{20}\ensuremath{\rightarrow}{\mathrm{GdCo}}_{2}{\mathrm{Zn}}_{20}\ensuremath{\rightarrow}{\mathrm{GdFe}}_{2}{\mathrm{Zn}}_{20}$ is presented and discussed.

Tópico:

Rare-earth and actinide compounds

Citaciones:

Citations: 8
8

Citaciones por año:

Altmétricas:

Paperbuzz Score: 0
0

Información de la Fuente:

SCImago Journal & Country Rank
FuentePhysical review. B./Physical review. B
Cuartil año de publicaciónNo disponible
Volumen95
Issue10
Páginas104407 - N/A
pISSNNo disponible
ISSN2469-9969

Enlaces e Identificadores:

Artículo de revista