In this research, the electrochemical impedance spectroscopy (EIS) and Tafel analysis were utilized to study the hot corrosion performance at 700[Formula: see text]C of air plasma-sprayed (APS) yttria-stabilized zirconia (YSZ) coatings with a NiCrAlY bond coat grown by high velocity oxygen fuel spraying (HVOF), deposited on an INCONEL 625 substrate, in contact with corrosive solids salts as vanadium pentoxide V 2 O 5 and sodium sulfate Na 2 SO 4 . The EIS data were interpreted based on proposed equivalent electrical circuits using a suitable fitting procedure performed with Echem Analyst TM Software. Phase transformations and microstructural development were examined using X-ray diffraction (XRD), with Rietveld refinement for quantitative phase analysis, scanning electron microscopy (SEM) was used to determinate the coating morphology and corrosion products. The XRD analysis indicated that the reaction between sodium vanadate (NaVO[Formula: see text] and yttrium oxide (Y 2 O[Formula: see text] produces yttrium vanadate (YVO[Formula: see text] and leads to the transformation from tetragonal to monoclinic zirconia phase.