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VOLUMETRIC PROPERTIES OF DL-ALANINE IN AQUEOUS SOLUTIONS OF TETRAFLUOROBORATE 1-BUTYL, 3-METHYLIMIDAZOLIUM AT DIFFERENT TEMPERATURES

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Abstract:

TETRAFLUOROBORATE 1-BUTYL, 3-METHYLIMIDAZOLIUM AT DIFFERENT TEMPERATURES.Densities of DL-alanine in aqueous ionic liquid, 1-butyl, 3-methylimidazolium tetrafluoroborate solutions were measured from 283.15 to 313.15 K.The densities measured were used to calculate apparent molar volumes (V f ), apparent molar volume limits (V f 0 ), transfer molar volume limits (DV f 0 ) and hydration number (NH).The behavior of (DV f 0 ) was interpreted in terms of solute-solvent interactions on the basis of the cosphere overlap model.The hydration numbers were positive and explained by dehydration and electrostriction.

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Chemical and Physical Properties in Aqueous Solutions

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Información de la Fuente:

SCImago Journal & Country Rank
FuenteQuímica Nova
Cuartil año de publicaciónNo disponible
Volumen39
IssueNo disponible
Páginas588 - 591
pISSN0100-4042
ISSNNo disponible

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