Ancient metallic artifacts from Battery San Rafael- Bocachica-Colombia, were analyzed for stereoscopic microscopy, Raman, FT-IRMIR and DRX, so as to determine their corrosion degree. In parallel optimization extracting of wax, present in the sugar cane bagasse, one popular agroindustrial waste zone, was the primary step in obtaining an corrosion ecoinhibidor propolis enriched, with molybdenum and zinc phosphate.