Similar yet different: A one-step regio- and diastereoselective synthesis of three new bis(pyrrolidine)[60]fullerenes, one cis-1 and two unprecedented cis-2 diastereoisomers, is reported. The compounds are easily purified using simple chromatographic techniques, and were fully characterized by spectroscopic techniques and X-ray crystallography. A mechanism for the isomeric conversion observed is proposed.
