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Formation of the Matrix‐Isolated Difluoromethylselanes XCF2SeH (X = H, Cl) Through Photolysis of Selenoacetic Acids, XCF2C(O)SeH

Acceso Abierto

ID Minciencias: ART-0000378909-14

Ranking: ART-ART_A1

Idioma: Inglés

Publicado: 19/07/2013

APC (est): No disponible

Abstract:

Abstract Two hitherto unknown difluoromethylselanes, HCF 2 SeH and ClCF 2 SeH, were formed by photolysis of difluoroselenoacetic and chlorodifluoroselenoacetic acids isolated in solid argon. The progress of the photolysis was monitored by FTIR spectroscopy. The photoproducts were identified by comparison of experimental with theoretically predicted spectra and reported spectra for known species. The photochemical decomposition mechanisms of HCF 2 C(O)SeH and ClCF 2 C(O)SeH is presented.

Tópico:

Inorganic Fluorides and Related Compounds

Citaciones:

Citaciones por año:

Altmétricas:

Información de la Fuente:

FuenteEuropean Journal of Inorganic Chemistry	Cuartil año de publicaciónNo disponible	Volumen2013
Issue26	Páginas4585 - 4594	pISSNNo disponible
ISSN1434-1948	Perfil OpenAlexhttps://openalex.org/S16435181

Enlaces e Identificadores:

Minciencias ID	ART-0000378909-14	Scienti ID	0000378909-14	Open_access URL	https://ri.conicet.gov.ar/bitstream/11336/93245/2/CONICET_Digital_Nro.703ff445-44ee-4f7f-b5a2-44c0a77c7a6f_A.pdf
Pdf URL	https://www.academia.edu/download/45903652/Formation_of_the_Matrix-Isolated_Difluor20160524-12020-1suhtre.pdf	Scholar URL	https://scholar.google.com/scholar?hl=en&as_sdt=0%2C5&q=info%3ASB8pQQ5mqfQJ%3Ascholar.google.com&btnG=	Openalex URL	https://openalex.org/W2077045090
Doi URL	https://doi.org/10.1002/ejic.201300322	Scholar citations URL	https://scholar.google.com/scholar?cites=17629734427727306568&as_sdt=2005&sciodt=0,5&hl=en

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