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Role of A -site cations in the metal-insulator transition in Pr 0.5Ca 0.5CoO

Acceso Abierto
ID Minciencias: ART-0000321176-34
Ranking: ART-GC_ART

Abstract:

Remarkable structural changes take place during the metal to insulator first-order transition in ${\text{Pr}}_{0.50}{\text{Ca}}_{0.50}{\text{CoO}}_{3}$: a contraction of the unit-cell volume, the bending of the Co-O-Co bond angle, and a decrease in (Pr,Ca)-O bond distance. However, the Co-O bond length and the volume of the ${\text{CoO}}_{6}$ octahedra remain almost unaltered during the transition. In view of these data and the absence of transition in ${({\text{Nd}}_{2/3}{\text{La}}_{1/3})}_{0.5}{\text{Ca}}_{0.5}{\text{CoO}}_{3}$, we review the current spin-state transition picture, emphasizing that an active role is played by the $A$-site Pr cations that could be related with the effect of Pr in 123 superconducting cuprates.

Tópico:

Magnetic and transport properties of perovskites and related materials

Citaciones:

Citations: 38
38

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Información de la Fuente:

SCImago Journal & Country Rank
FuentePhysical Review B
Cuartil año de publicaciónNo disponible
Volumen81
Issue5
PáginasNo disponible
pISSNNo disponible
ISSN1550-235X

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Publicaciones editoriales no especializadas