In this article, we introduce the σ-PWB extensions and construct the theory of Gröbner bases for the left ideals of them. We prove the Hilbert's basis theorem and the division algorithm for this more general class of Poincaré–Birkhoff–Witt extensions. For the particular case of bijective and quasi-commutative σ-PWB extensions, we implement the Buchberger's algorithm for computing Gröbner bases of left ideals.