This paper reports the characterization and photoactivity of Ag-TiO 2 materials using different amounts of silver during the hydrothermal synthesis. Photocatalysts were characterized by means of TEM, XPS, XRD, DRS, and N 2 sorption isotherms to determine the textural properties. The photocatalyst's configuration was observed to be as anatase-brookite mixed phase particles with Ag partially oxidized aggregates on the TiO 2 surface, which increased visible light absorption of the material. Moreover, photoproduction of singlet oxygen was followed by EPR analysis under visible light irradiations following the formation of TEMPOL. Such photoproduction was totally decreased by using the singlet oxygen scavenger DABCO. Photocatalysts were tested towards the photocatalytic disinfection of water suing a solar light simulator and an interior-light irradiation setup. Results evidenced an increase in the photooxidative effect of TiO 2 , while dark processes evidenced that part of the inactivation process is due to the Ag-TiO 2 surface bactericidal effect and possible lixiviated Ag + .