Superlattices of antiferromagnetic (AF) La1∕3Ca2∕3MnO3 and ferromagnetic (F) La2∕3Ca1∕3MnO3 were grown using sputtering technique. The AF layer thickness ranged between 3.9nm⩽tAF⩽15.6nm while the F layer thickness was kept constant (7.8 nm). Hysteresis measurements after field cooling, show an exchange bias up to a temperature of ∼100K. Surprisingly, the saturation magnetization increases with antiferromagnetic layer thickness and can exceed the expected bulk value for the La2∕3Ca1∕3MnO3 composition, whereas the interface coupling energy between the AF and F layers derived from the exchange bias is constant. This suggests that magnetization depth profile extends beyond the chemical doping interface.